The groundmass contains interstitial quartz or tridymite or cristobalite.
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The main 3 polymorphs are quartz, cristobalite, and tridymite.
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Cristobalite, which is shown here in this magnified view, is found on Earth in volcanic lava flows.
From the sciencedaily.com
The ash also contained large amounts of cristobalite, a form of silica and a known hazard which can cause silicosis.
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Other phases, e.g. the higher-temperature phases tridymite and cristobalite, are not significant for oscillators.
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Thus although tridymite and cristobalite are common minerals in ignimbrites, they may not be primary magmatic minerals.
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The crystals, called cristobalite and tridymite, are known to reside in comets, in volcanic lava flows on Earth, and in some meteorites that land on Earth.
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Note also that both high temperature minerals, cristobalite and tridymite, have both a lower density and index of refraction than quartz.
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Commonly in most felsic ignimbrites the quartz polymorphs cristobalite and tridymite are usually found within the welded tuffs and breccias.
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More examples
A white mineral consisting of silica; found in volcanic rocks
The mineral cristobalite is a high-temperature polymorph of quartz, meaning that it is composed of the same chemistry, SiO2, but has a different structure. Both quartz and cristobalite are polymorphs with all the members of the Quartz Group which also include coesite, tridymite and stishovite. ...
Crystalline form of silica that has a high expansion and contraction rate. (2)
Simplest crystallographic form of SiO2.
A crystalline form of silica formed at temperatures above Cone 9. Cristobalite undergoes an inversion like Quartz, but at the lower temperature of 439F, and with a much higher volumetric change of 3%.
An allotropic form of crystalline silica used in dental casting investments